Molecularly tailorable metal oxide clusters ensured robust interfacial connection in inverted perovskite solar cells

This article introduces a novel approach to enhancing the performance and stability of inverted perovskite solar cells (PVSCs) using molecularly customizable cyclic titanium oxide clusters (CTOCs). These clusters form a robust interlayer between perovskite and C60 electron-transporting layers, addressing challenges like recombination losses and ion migration. Tailored with fluoroaryl groups, CTOCs effectively passivate surface defects, improve electron mobility, and create a strong interfacial connection. Devices integrated with these clusters achieve a power conversion efficiency of 25.6% and demonstrate remarkable stability, retaining 98% efficiency after 1,500 hours of continuous operation. The findings showcase CTOCs’ potential for advancing perovskite photovoltaics through improved durability and high efficiency.

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https://www.science.org/doi/10.1126/sciadv.adq1150


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